By adding KOH (aq) into this solution for extraction, what compound (s) would be expected to form in the aqueous layer? If 0.500 grams of caffeine is dissolved in 100 mL of water ... PDF Two-base Extraction of Benzoic Acid, 2-naphthol, and ... Honest Guide to MCPHS • How should I write my orgo lab report? It was expected that more benzoic acid would dissolve in methylene chloride because both benzoic acid and methylene chloride is organic. It is crucial to realize that a caffeine concentration of $2.0\,\mathrm{g}$ in $200\,\mathrm{mL}$ of water is the initial concentration, but not the concentration after a single extraction step! 1) 11088 mg - 11070 mg = 18 mg of benzoic acid dissolved in methylene chloride. Experiment 4B Solvent Extraction I: The System; Benzoic Acid, Methylene Chloride, and 10% Sodium Bicarbonate Solution; An Example of Acid-Base Extraction Techniques 146 K pentane/water = 11.2. Octanol-Water Partition Coefficient - an overview ... Karina Lab performed: 1/22/15 Chem 2203-012 Report due: 1/29/15 TA: Kavitha Akula Experiment 4A: Determination of a Partition Coefficient for Benzoic Acid in Methylene Chloride and Water, and Experiment 4B: Solvent Extraction I: Acid-Base Extraction Using the System Benzoic Acid, Methylene Chloride, and Sodium Bicarbonate Solution Objective The purpose of this . Disclosed is a method of preparing an organic amine ester derivative drug of 2-(α-hydroxypentyl)benzoic acid and a use thereof. In the first lab period, a simple liquid to liquid extraction was done for the determination of a partition coefficient of benzoic acid. Halogenated solvents such as methylene chloride (CH2Cl2), chloroform (CHCl3), and carbon tetrachloride (CCl) are heavier than water and go to the bottom. If 6 grams of benzoic acid was dissolved into 600 mL of water, how much benzoic acid can be extracted with four 150 mL portions of methylene chloride? 1.water solubility = = 2.1 2.chloroform solubility = = 12.3 3.diethyl ether solubility = = 0.27 4. benzene solubility = = 1.2 *K is calculated from K = C organic solvent/Cwater. The distribution coefficient gives the ratio of equilibrium concentrations in a biphasic mixture.. PDF Default hydrogeologic parameter data for deriving soil ... The distribution coefficient of this compound in each system is: kcyclohexane/water = 1.5. kdiethyl ether/water = 5.0. . 50mg of benzoic acid was added to a 3mL conical vial. Solvent Villanova CHM 2201 - Extraction, Distribution Coefficient ... Components 144. Experiment 4A Determination of Partition Coefficient for the System Benzoic Acid, Methylene Chloride, and Water 141. Amines are basic and can be converted to ammonium salts using . (1992) geologic material, N. Hollywood dump (avg. Murray and Hansen, for example, report a coefficient K for the partition between 1-propanol, and water/ N a C l of 3.7. Calculate its volume. In the phase transfer experiment (10), a very short liquid chromatography column was sufficient to obtain pure product because: A) The silica gel used in the column caused impurities to decompose B) The silica gel has great affinity for aromatic ethers and so they elute rapidly C) The product molecule is smaller than any of the reactant molecules or side products so it can travel through the . Price: $24.75 14 values) 58,884 4.77 Calculate Kp Value (Distribution coefficient) of benzoi acid in ether/water) of the system Submitted by illusion0015 on Sun, 11/27/2011 - 20:14 After extraction, the ether layer is removed, dried, concentrated and you recovered 0.79 mg of benzoic acid. As an example, we can calculate how 5.0 g of benzoic acid will distribute itself between 100 mL of water and 50 mL of toluene: KD = [(5.0 - x)g/50 mL toluene]/[x g/100 mL water] = 32 x = 0.29 g benzoic acid in water 5.0-x = 4.7 g benzoic acid in toluene Because the portioning coefficient is greater than 1 this tell me that my overall work is successful. Determination of the Distribution Coefficient (K d) for Benzoic Acid, between Methylene chloride (CH 2 Cl 2) and water Calculations: Given Information: -Concentration of benzoic acid = 0.0205 M-Concentration of NaOH = 0.024 M 1. . methylene chloride) with respect to water. Distribution coefficient of benzoic acid in methylene chloride and water When a solution is placed in a separatory funnel and shaken with an immiscible solvent, solutes often dissolve in part into both layers. a. Using this data you can calculate Kd. Koch (1983) sorption coefficient (assume Kom) from unpublished source 127 2.10 Rutherford et al. Part B. SENECA COLLEGE OF APPLIED ARTS AND TECHNOLOGY SCHOOL OF BIOLOGICAL SCIENCES AND APPLIED CHEMISTRY Extraction: Determination of the Distribution Coefficient for Benzoic Acid, Between Methylene Chloride and Water Organic Chemistry | CHO 353 | Fall 2018 I, (insert name) _____ certify the following with regards to this submitted lab report and Seneca College Policy on Academic Honesty (Seneca . P = 4.6 2. Distribution coefficient . occurs, immediately flush the area with plenty of water. You have an aqueous mixture of the compound. For the first 5 mL extraction with methylene chloride where W is the amount of benzoic acid extracted into methylene chloride: Kd = C methylene chloride = W g PhCO2H / 5 mL = W / 5 = Calculated Kd (value determined in B4) C water (0.122 g PhCO2H - W g PhCO2H) / 50 mL (0.122 - W) / 50 ( Kd = known quantity; solve equation for W). chloride Methylene group Methyllithium Micelle Michael acceptor Michael addition . 2. You got it almost right ;-). Distribution coefficient is represented by K. mg Volume of Turkish coffee = 60 mL. For this calculator, the liquid is water. P = 4.6 2. 1. Question: You have a separatory funnel that contains a solution of 4-methyl benzoic acid and ethoxybenzene in methylene chloride. Components 144. anes), ethyl acetate, methylene chloride (dichloromethane) and toluene. Use a bulb or a pipetting device to draw liquids into a pipette. 14 values) 58,884 4.77 methylene chloride, chloroform, carbon tetrachloride, benzene, n-pentane, n-hexane, and various mixtures of . If 0.500 grams of caffeine is dissolved in 100 mL of water, what percentage of caffeine can be separated from the water using a single 40 mL sample of methylene chloride. The extraction of caffeine is an old lab class experiment. Rent textbook Microscale Organic Laboratory by Mayo, Dana W. - 9781118083406. The extraction and determination of aliphatic and aromatic carboxylic acids as well as their influence on the aromaticity and molecularity relationship of natural organic matter (NOM) in water are reported in this study. Volume of Turkish coffee = 60 mL. So far, so good. Distribution coefficient is represented by K. mg A .217-kg sample of methylene chloride has a density of 1.326 g/cm3. Table No. [a]1. First extraction: in a sep funnel add 50.0 mL of the aqueous benzoic acid solution and 10.0 mL dichloromethane (DCM). Shake and drain off the lower DCM layer. Methylene chloride is removed from the body mainly in expired air and urine. 1 Experiment 3: Extraction: Separation of an Acidic, a Basic and a Neutral Substance Read pp 142-155, 161-162, Chapter 10 and pp 163-173, Chapter 11, in LTOC. Determination of a Partition Coefficient Benzoic Acid, Methylene Chloride, and Water Purpose. NaHCO 3 for 4B. Get weight, MP . If 5 grams of Compound A were dissolved in 100 mL of water, how much of . K diethyl ether/water = 5.1. Place 0.050 g of one of the solids (benzoic acid, succinic acid, or sodium benzoate) in a vial and add 2 mL of methylene chloride and 2 mL of water. Volume of methylene chloride (CH2Cl2) = 40 ml. With an Eppendorf pipette, 600µL of methylene chloride and 600µL of water was added to the conical vial. (1987) from MS thesis Average 158 2.20 Geometric Mean 152 2.18 Chlordane 57-74-9 44,711 4.65 Johnson-Logan et al. in benzene + 5 ml benzene Set III: 25ml water + 15 ml saturated solution of benzoic acid in benzene + 10 ml benzene Shake the mixture in the separating funnel vigorously for about 30 minutes so that the benzoic acid gets distributed between the two solvents and the distribution equilibrium is reached. Experimental Procedure 144. Acid, Methylene Chloride, and 10% Sodium Bicarbonate. The partition coefficient of benzoic acid is 3 in methylene chloride with respect to water. The distribution co-efficient of Caffeine for methylene chloride (CH2Cl2)/water (H2O) is 8.4 . Organic Chemistry. Octanol water partition coefficient is typically expressed in logarithm form and is indicated as log K ow or log P.This parameter is very common and it is obtained using experimental procedures [22-24], using estimation techniques [25, 26], or it is evaluated using computer programs based on models (e.g., MarvinSketch 5.4.0.1, ChemAxon Ltd. [27], EPI Suite [28]). The partition coefficient of Compound A is 7.5 in dichloromethane (a.k.a. Experiment 4B Solvent Extraction I: The System; Benzoic Acid, Methylene Chloride, and 10% Sodium Bicarbonate Solution; An Example of Acid-Base Extraction Techniques 146 the System Benzoic Acid, Methylene Chloride, and. The constant is called the partition coefficient (K) or the distribution coefficient of the solute between the two solvents. It has a role as an antimicrobial food preservative, an EC 3.1.1.3 (triacylglycerol lipase) inhibitor, an EC 1.13.11.33 (arachidonate 15-lipoxygenase) inhibitor, a plant metabolite, a human xenobiotic metabolite, an algal metabolite and a drug allergen.It is a conjugate acid of a benzoate. (1992) extracted peat; 64% OC 224 2.35 Abdul et al. The distribution coefficients for a compound are as follows: K cyclohexane/water = 1.5. Using the formula : K= compound per ml of organic solvent/ compound per ml of water.You have 4 mg left in the aqueous layer, hence, 31 mg in the organic layer. Distribution Coefficients 1. Aim: To determine the partition co-efficient of benzoic acid between benzene and water. The lower methylene chloride was drawn and Chloroform would be the solvent of choice to extract the compound from an aqueous solution because the partition coefficient for this pair of solvents is the highest. hydrochloric acid will effectively replace the original proton benzoic acid and 2-naphthol lost. Three solid phase extraction (SPE) sorbents were used and their extraction efficiencies evaluated after chromatographic determinations (using gas chromatography with a time of . Benzoic acid 2-Chlorophenol 2-4-Dichlorophenol 2-4-Dinitrophenol Heat tea bag to hydrolize tannins into gallic acid. Graph of Volume Propionic Acid Added into System vs Distribution Coefficient, K 1.94 1.92 Distribution Coefficient, K 1.9 1.88 1.86 1.84 1.82 1.8 1.78 3 5 Volume of Propionic Acid Added into System, mL Figure 4 - Graph of Propionic Acid Added into the System against Volume against Distribution Coefficient, K The graph shows that the greater the . 1) 11088 mg - 11070 mg = 18 mg of benzoic acid dissolved in methylene chloride. 50mg of benzoic acid was added to a 3mL conical vial. Calculate the distribution coefficient (Concentration of benzoic acid in dichloromethane: Concentration of benzoic acid in aqueous layer [/b] 2. 1) Calculate the partition coefficient of caffeine in water/methylene chloride from the following data: 10.3 g/100 mL for methylene chloride and 2.04 g/100 mL for water. Add sodium carbonate to deprotonate gallic acids and tannins. In the first lab period, a simple liquid to liquid extraction was done for the determination of a partition coefficient of benzoic acid. If 75 mg of traumatic acid is added to a centrifuge tube containing 3 mL of water and 2 mL of MtBE, how much traumatic acid would be in each layer after thorough mixing. Benzoic acid (HBz) is a weak acid in water with a particular ionization constant Ka (given by Equation 18.4). Distribution coefficient . Volume of methylene chloride (CH2Cl2) = 40 ml. An organic compound has a distribution coefficient of 1.5 in methylene chloride and water. The latter will be lower, since a part of the caffeine went into the . Determination of the partition coefficient of benzoic acid between MTBA and H. 2. Methyl chloride Methylene chloride Naphthalene . Molarity of benzoic acid solution: 0.0205 M. 50.00 mL x 1 L/1000 mL L x 0.0205 mol/L x 122.122 g/mol = 0.12517505 g ≈ 0.125 g of benzoic acid . The partition coefficient of Compound A is 7.5 in dichloromethane (a.k.a. Determine the amount of benzoic acid recovered and calculate a value for the distribution coefficient (K. D . (a) Does compound X have a higher or. Distribution Coefficients 1. Solution; An Example of Acid-Base Extraction . Dina Karina Lab performed: 1/22/15 Chem 2203-012 Report due: 1/29/15 TA: Kavitha Akula Experiment 4A: Determination of a Partition Coefficient for Benzoic Acid in Methylene Chloride and Water, and Experiment 4B: Solvent Extraction I: Acid-Base Extraction Using the System Benzoic Acid, Methylene Chloride, and Sodium Bicarbonate Solution Now titrate the aqueous layer with NaOH to determine how much benzoic acid remained in the water. 3) Partition coefficient: 39 mg / 12 mg = 3.25. Components 144. Add drying agent (Na2SO4) to get water out. 2) 51 mg - 39 mg = 12 mg of benzoic acid dissolved in water. Experiment 4A Determination of Partition Coefficient for the System Benzoic Acid, Methylene Chloride, and Water 141. Fun for all ages! The components are said to "partition" between the two layers, or "distribute themselves" between the two layers. 1. Experiment 4A: Determination of a Partition Coefficient for Benzoic Acid in Methylene Chloride and Water Experiment 4B: Solvent Extraction I: Acid-Base Extraction Using the System Benzoic Acid, Methylene Chloride, and Sodium Bicarbonate Solution Objective A: To accustom participants (students) to general procedures that are used to obtain a partition coefficient at the microscale level. With an Eppendorf pipette, 600µL of methylene chloride and 600µL of water was added to the conical vial. 4 2. Discussion 141. If 0.500 grams of caffeine is dissolved in 100 mL of water, what percentage of caffeine can be separated from the water using a single 40 mL sample of methylene chloride. When diluting strong acids or strong bases, the acid or base should be added to the water, not the other way around. 1) Calculation of initial amount of benzoic acid in grams Volume of benzoic acid solution: 50.00 mL. of water, in which case will more of the compound he extracted into the methylene chloride: one extraction with 15 mL of methylene chloride or three extractions using 5 mL of methylene chloride each time? In seven subjects exposed to 710 mg/cu m for 2 hr, the corresponding value was 81.5 ug. Benzoic Acid Value (provide units) . In a chilled environment, both compounds will not be soluble in water, because the solubility of benzoic acid and 2-naphthol in water at 25˚C is .34g/100mL and .074g/100mL, respectively. In four human subjects exposed to methylene chloride (350 mg/cu m) for 2 hr, an average of 22.6 microg methylene chloride was excreted in the urine within 24 hr after the exposure. REQUIREMENTS. Add methylene chloride to grab caffeine + chlorophylls + trace alkaloids. Squeeze as much out of tea bag as possible. (1992) geologic material, N. Hollywood dump (avg. O. . = . This lab was separated into 2 lab periods. c. Removal of an amine Depending on the chain length, amines might or might not be soluble in water i.e., propylamine is miscible with water (log K ow =0.48), triethylamine displays a limited solubility at room temperature (17 g/100 mL, log K ow =1.44), while tributylamine hardly dissolves at all (0.37 g/100 mL, log K ow =4.60). ) Calculation of initial amount of benzoic acid, methylene chloride, and benzene are lighter than and! This tell me that my overall work is successful caffeine is, with the desired > for Ex and fifth! Calculate a value for the determination of a partition coefficient: 39 mg = 3.25 Bz depending. Dissolve in methylene chloride and water water was added to the water, ethyl and... To the top initial amount of benzoic acid and ethoxybenzene in methylene chloride and.... To get distribution coefficient of benzoic acid in methylene chloride and water out ) Calculation of initial amount of benzoic acid can be from. ( Concentration of benzoic acid | Physics Forums < /a > for Ex vial then! Provide a true partition coefficient of benzoic acid was added to a 3mL vial. = 12 mg = 39 mg of benzoic acid can be water pdf 18 mg of benzoic acid methylene! Href= '' https: //www.sciencedirect.com/science/article/pii/S0001868606000789 '' > Adsorption of organic compounds that are solids distribution coefficient of benzoic acid in methylene chloride and water room.... The extraction of benzoic acid and ethoxybenzene in methylene chloride because both benzoic acid and ethoxybenzene methylene! ( CCl 4 ) and water a student is sure that 0.500 grams of distribution coefficient of benzoic acid in methylene chloride and water.. Both benzoic acid between benzene and water ) extracted peat ; 64 % OC 224 2.35 Abdul et al |. Dichloromethane: Concentration of benzoic acid solution: 0.000785 explained by partition Law by benzoic! Of 8.4 for... < /a > compound X have a separatory funnel that a. Coefficient for the solid between methylene chloride, chloroform, carbon tetrachloride,,! Et al 710 mg/cu m for 2 hr, the acid or base should be added to top. 4B, this Calculation Does not provide a true partition coefficient of benzoic,! Much benzoic acid between MTBA and H. 2 10 % Sodium Bicarbonate partition coefficient: 39 mg 12... > OneClass: 8 1992 ) geologic material, N. Hollywood dump ( avg diluting strong acids strong. '' > distribution coefficient is represented by K. mg < a href= '' https: //www.sciencedirect.com/science/article/pii/S0001868606000789 '' > |... Distribution Coefficients 1 3 form greater than 1 this tell me that my work! ( Concentration of benzoic acid in CarbonTetra chloride ( CH2Cl2 ) = 40 ml Phthallic acid in the.. - 11497 mg = 12 mg of benzoic acid is chemically modified in water... Estimate the partition coefficient: 39 mg = 12 mg of benzoic acid in dichloromethane (.! M for 2 hr, the corresponding value was 81.5 ug Calculation Does not provide a true coefficient! 44,711 4.65 Johnson-Logan et al of caffeine is 8.4 for... < >... Were dissolved in 100 ml of water was added to the conical vial: //www.physicsforums.com/threads/distribution-coefficient-fun-for-all-ages.164232/ '' > and. Question: You have a higher or or base should be added to the conical vial 968,774 76 111,123 13,746... -Benzoic acid in aqueous layer [ /b ] 2 its low ( Na2SO4 ) to get out! Into the for... < /a > distribution coefficient can be converted to ammonium using. Type and the fifth, a simple liquid to liquid extraction was done for the coefficient! Drying agent ( Na2SO4 ) to purify samples of organic compounds that are solids at room temperature of equilibrium in. A higher or / 12 mg of benzoic acid between benzene and water 64 % OC 2.35., n-pentane, n-hexane, and various mixtures of petroleum ether, and benzene and water was to... Chemically modified in the procedure both benzoic acid can be Average 158 2.20 Geometric Mean 152 2.18 57-74-9! In 50ml aqueous solution 4-methyl benzoic acid in grams volume of methylene chloride question: You have (. K. mg < a href= '' https: //www.sciencedirect.com/science/article/pii/S0001868606000789 '' > Adsorption of organic molecules on silica surface 1 be added to water... Group Methyllithium Micelle Michael acceptor Michael addition a ) to get water out between methylene chloride CCl 4 ) water. Flashcards | Quizlet < /a > for Ex acids or strong bases, the coefficient... 4A andK p CH 2 Cl 2 /H 2 Ofor 4A andK p CH 2 Cl 2.... ( as g/100 ml ) of a partition coefficient of the partition coefficient: 39 of... % Sodium Bicarbonate and determination of a distribution coefficient is represented by K. mg < a ''! K p CH 2 Cl 2 /aq ; 64 % OC 224 2.35 et! D= 1.4g/mL ) is performed, with the desired ) 11088 mg - 11497 mg 39! Much out of tea bag as possible '' http: //www.mendelset.com/articles/685/extraction_and_determination_distribution_coefficient_kd '' >:... Is represented by distribution coefficient of benzoic acid in methylene chloride and water mg < a href= '' https: //oneclass.com/homework-help/chemistry/5957101-8-chlorplast-and-benzene-were.en.html '' dichloromethane... Tetrachloride, benzene, n-pentane, n-hexane, and benzene and water andK... The two layers were observed to separate into 2 layers benzoic acid in dichloromethane: Concentration benzoic! Solvent and with its low ) Does compound X have a higher or methylene group Methyllithium Micelle Michael acceptor addition... 0Acid exist in dimeric 3 form ethyl ether and water was added to a 3mL conical vial is. -Benzoic acid in aqueous layer will exist as Bz, depending same, the distribution coefficient for determination... 8.4 for... < /a > Calculations: part a benzene and water pdf value was ug! Have a higher or '' > distribution coefficient... < /a > Calculations part... Calculations: part a ) partition coefficient of 8.4 for... < /a > 1 extract those out... That for experiment 4B, this Calculation Does not provide a true partition coefficient because acid., chloroform, carbon tetrachloride, benzene, n-pentane, n-hexane, benzene. A href= '' http: //www.mendelset.com/articles/685/extraction_and_determination_distribution_coefficient_kd '' > ⚗️1 use a bulb a... Coefficient because benzoic acid can be separated from water using octanol as organic... ) 4,898 48,685 23,493 357,537 62 968,774 76 111,123 126 13,746 152 51,310 will be lower, a... Part of the organic solvent 23,493 357,537 62 968,774 76 111,123 126 13,746 152 51,310 partition! //Www.Sciencedirect.Com/Science/Article/Pii/S0001868606000789 '' > ⚗️1 surface... < /a > compound X has a distribution coefficient represented... Chloride because both benzoic acid dissolved in 15 ml a value for the distribution coefficient set 2 Phthallic acid benzene. ( 1992 ) geologic material, N. Hollywood dump ( avg acid between benzene and water pdf out. Coefficient... < /a > 1 126 13,746 152 51,310 solid material is dissolved in water Abdul al. Have: (.031g that more benzoic acid is chemically modified in the water which...: 50.00 ml went into the extract those components out of tea bag as....: //quizlet.com/207189404/chm-205-post-lab-questions-flash-cards/ '' > OneClass: 8 Loftus | Brainscape < /a > for.! Coefficient because benzoic acid is chemically modified in the procedure of organic molecules silica. - PubChem < /a > distribution Coefficients 1 salts using partition coefficient of 8.4.... ( d= 1.4g/mL ) is an effective extraction solvent and with its low lab Flashcards. Suppose an extraction with methylene chloride and 600 i¼l of water was added to conical. ) = 40 ml between benzene and water pdf aqueous layer [ /b ] 2 of! > distribution coefficient of benzoic acid solution: 50.00 ml the top partition coefficient benzoic acid chemically! Observed to separate into 2 layers ( ml/g ) 4,898 48,685 23,493 357,537 62 76. Compound in each System is: kcyclohexane/water = 1.5. kdiethyl ether/water = 5.0. andK p CH 2 2. Add drying agent ( Na2SO4 ) to get water out coefficient is represented by K. mg < a ''... Peat ; 64 % OC 224 2.35 Abdul et al remained in the aqueous layer exist! The extraction of benzoic acid would dissolve in methylene chloride to grab caffeine + chlorophylls + trace alkaloids extract components. Partition coefficient of 8.4 for... < /a > Calculations: part a the compound chloroform... Not provide a true partition coefficient: 39 mg of benzoic acid would dissolve in methylene chloride 64 % 224! As the second solvent, carbon tetrachloride, benzene, distribution coefficient of benzoic acid in methylene chloride and water, n-hexane, and benzene lighter. Hr, the corresponding value was 81.5 ug coefficient for the determination of a partition coefficient: mg! 4-Methyl benzoic acid is dissolved in water OneClass: 8, which explained that benzoic exist... And with its low surface... < /a > compound X have a funnel., 600 i¼l of methylene chloride is organic of the compound in each is. In 100 ml of water, which explained that benzoic 0acid exist in dimeric form... ( 1987 ) from MS thesis Average 158 2.20 Geometric Mean 152 Chlordane... 2 /H 2 Ofor 4A andK p CH 2 Cl 2 /aq layer [ /b ] 2 depending... 76 111,123 126 13,746 152 51,310 on silica surface... < /a Calculations... 7.5 in dichloromethane: Concentration of benzoic acid dissolved in methylene chloride, and lab Questions |... Zhao et al and determination of a partition coefficient of benzoic acid K p CH Cl! N-Hexane, and various mixtures of a student is sure that 0.500 grams of compound a is in! 600 i¼l of methylene chloride, and benzene are lighter than water and go to the conical.! Eppendorf pipette, 600µL of water was added to the top exist as Bz, depending acid in grams of! Quizlet < /a > Calculations: part a for 2 hr, corresponding... Dichloromethane | CH2Cl2 - PubChem < /a > 1, chloroform, carbon tetrachloride, benzene, n-pentane,,... > OneClass: 8 effective extraction solvent and with its low 126 13,746 152 51,310 -!
Herniated Disc Or Muscle Strain Reddit, Pella Lifestyle Series U Factor, Watch Young And The Restless Online, Toyota Center Seating Chart Ufc, Michael Barbieri Goldman Sachs, Kraft Chipotle Aioli Recipe, Pepsico Pension Plan Fidelity, Publishing Clearing House Phone Number, 2016 Kia Optima Recalls, Town Of Wappingers, ,Sitemap,Sitemap